Aha! Chemistry with Prof Bob
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  • NAVIGATION
    • Table of contents
    • Index
    • TALK WITH PROF BOB?
  • LEARNING MODULES
    • Chapter 02 Stuff, matter: What is it? >
      • 0200 Stuff, matter: A theory of atoms
      • 0201 Atoms: The building blocks of all stuff
      • 0202 People classifying stuffs. Why?
    • Chapter 05 Chemical reactions, chemical equations >
      • 0500 Chemical reactions vs. chemical equations. Overview
      • 0501 Chemical amount and its unit of measurement, mole
      • 0502 The Avogadro constant: How many is that?
      • 0503 The Avogadro constant: Why is it that number?
      • 0504 Chemical formulas: What can they tell us??
      • 0505 Chemical equations: What can they tell us?
      • 0506 Limiting reactants: How much reaction can happen?
      • 0507 Balanced chemical equations: What are they?
      • 0508 Chemical reactions as competitions
    • Chapter 09 Aqueous solutions >
      • 0901 What is a solution? And what is not?
      • 0902 Miscibility of liquids in each other
      • 0903 Like dissolves like? Shades of grey
      • 0905 Dissolution of ionic salts in water: A competition
      • 0906 Can we predict solubilities of salts?
      • 0907 Solution concentration
      • 0908 Chemical species, speciation in aqueous solution
      • 0909 Solutes: Electrolytes or non-electrolytes?
      • 0910 Electrolytes - strong or weak?
      • 0911 Concentrated, dilute, strong, weak
      • 0912 Species concentration vs. solution concentration
      • 0913 Weak electrolytes: Getting quantitative
    • Chapter 11: Dynamic chemical equilibrium >
      • 1100 Dynamic chemical equilibrium: Overview
      • 1101 Visualising dynamic chemical equilibrium
      • 1102 The jargon of chemical equilibrium
      • 1103 Equilibrium constants: The law of equilibrium
      • 1104 The law of equilibrium: an analogy
    • Chapter 22 Spectroscopy >
      • 2200 Spectroscopy: Overview and preview
      • 2201 Quantisation of forms of energy
      • 2202 Light: Wave-particle "duality"
      • 2203 Ultraviolet-visible spectroscopy
      • 2204 Beer’s law: How much light is transmitted?
    • Chapter 27 The greenhouse effect, climate change >
      • 2700 The greenhouse effect: overview
      • 2701 Is Earth in energy balance?
      • 2702 CO2 in the atmosphere before 1800
      • 2703 So little CO2! Pffft?
      • 2704 Does CO2 affect Earth's energy balance?
      • 2705 The "greenhouse effect"
      • 2706 Why does CO2 absorb radiation from Earth?
      • 2707 The "enhanced greenhouse effect"
      • 2708 Why doesn't CO2 absorb the radiation from the sun?
      • 2709 Why are N2 and O2 not greenhouse gases?
      • 2710 Doesn't water vapour absorb all the IR?
      • 2711 Carbon dioxide from our cars
      • 2712 The source of energy from combustion
      • 2713 Comparing fuels as energy sources
      • 2714 Methane: How does it compare as a GHG?
      • 2715 Different sorts of pollution of the atmosphere
      • 2716 "Acidification" of seawater
    • Chapter 27 Communicating chemistry >
      • 2700 Overview, preview
      • 2703 The jargon we use
  • TEACHERS' CORNER
    • T01 Communicating chemistry
    • T02 Beer's law
    • T03 Professional amnesia of the chemistry teaching professio
    • T04 Law of equilibrium
    • T05 Visusalizing dynamic chemical equilibrium
    • Information vs. knowledge
  • PERSONAL GALLERY
    • Family
    • Travel
    • Playful dolphins
    • The University of Western Australia
    • Kings Park
    • Perth
    • At work
    • 999 Thermodynamics
Module 2704


​

Does carbon dioxide affect Earth’s energy balance?

What is the effect of carbon dioxide in our atmosphere?
​

What would be our average temperature if there were no carbon dioxide?

Is carbon dioxide good stuff or bad?

In this module, we focus on the effect on temperature due to the presence of carbon dioxide in our atmosphere, and the magnitude of the effect. Postpone for now questions of how carbon dioxide exerts an effect (Module 2705 The "greenhouse effect"), and why it does its thing (Module 2706 Why do carbon dioxide molecules absorb radiations emitted from Earth?).
​
Here is how it works (Level 1 of understanding)

Carbon dioxide molecules "capture" some of the radiation emitted from Earth's surface, and which would otherwise go off on a long journey into deep space.
​
Imagine the Earth in a state of energy balance (See Module 2701 Is Earth in energy balance?), the temperature staying constant. And then we inject some carbon dioxide into the atmosphere. So not as much outgoing radiation (heat energy) escapes from Earth, and so the rate of incoming radiation is more than the rate of emitted radiation. Temperature will increase.
​
Let's look at another way - the reverse. Suppose that Earth is in a state of energy balance, and we can somehow instantaneously remove all of the carbon dioxide that is in the atmosphere. Since there are now no carbon dioxide molecules to "capture" the outgoing heat energy, the rate of emission of energy into space will increase. There is no longer energy balance: the rate of outgoing radiation exceeds the rate of incoming radiation. The temperature will decrease.

So carbon dioxide is keeping us warmer than would otherwise be the case.

​
By how much is Earth warmer?
​
According to climate scientists’ calculations, Earth is warmer by 33 °C than it would be without carbon dioxide in the atmosphere. Huge!
​
The average temperature of the surface of Earth is 15 °C. So without carbon dioxide in the atmosphere, the average temperature would be – 18 °C


Who would prefer that the average temperature is -18 °C rather than + 15 °C? Not many of us, other than perhaps polar bears?

​
So, is carbon dioxide a good stuff, or a bad stuff?

Here is an approximate representation of a carbon dioxide molecule - not that anyone has ever seen one of them.
​
Picture
In a carbon dioxide molecule, two oxygen atoms are bonded to a carbon atom. The relative sizes shown are representative of best estimates. The colours shown are used just to distinguish the atoms: carbon atoms are not grey, and oxygen atoms are not red. Are they?
But carbon dioxide is getting a bad wrap. It represents gloom and doom ....

Picture
Is carbon dioxide evil? The daily press and the popular science press have nothing good to say about it.
So I am beginning to wonder if a molecule of carbon dioxide really looks different from that above .......

Picture
A carbon dioxide molecule?
But then, if there were no carbon dioxide in the atmosphere, our average temperature would be -18 °C.  That sounds like a pretty good substance to me! Revised (again) image of carbon dioxide molecules .....

Picture
A carbon dioxide molecule - all sweetness and goodness?
Maybe carbon dioxide is both good and bad - depending on context. The "dual nature" of carbon dioxide?

Its good side is discussed above and in Module 2705 The "greenhouse effect". It's not-so-good side will become apparent in Module 2707 The "enhanced greenhouse effect".


Picture
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  • HOME
  • NAVIGATION
    • Table of contents
    • Index
    • TALK WITH PROF BOB?
  • LEARNING MODULES
    • Chapter 02 Stuff, matter: What is it? >
      • 0200 Stuff, matter: A theory of atoms
      • 0201 Atoms: The building blocks of all stuff
      • 0202 People classifying stuffs. Why?
    • Chapter 05 Chemical reactions, chemical equations >
      • 0500 Chemical reactions vs. chemical equations. Overview
      • 0501 Chemical amount and its unit of measurement, mole
      • 0502 The Avogadro constant: How many is that?
      • 0503 The Avogadro constant: Why is it that number?
      • 0504 Chemical formulas: What can they tell us??
      • 0505 Chemical equations: What can they tell us?
      • 0506 Limiting reactants: How much reaction can happen?
      • 0507 Balanced chemical equations: What are they?
      • 0508 Chemical reactions as competitions
    • Chapter 09 Aqueous solutions >
      • 0901 What is a solution? And what is not?
      • 0902 Miscibility of liquids in each other
      • 0903 Like dissolves like? Shades of grey
      • 0905 Dissolution of ionic salts in water: A competition
      • 0906 Can we predict solubilities of salts?
      • 0907 Solution concentration
      • 0908 Chemical species, speciation in aqueous solution
      • 0909 Solutes: Electrolytes or non-electrolytes?
      • 0910 Electrolytes - strong or weak?
      • 0911 Concentrated, dilute, strong, weak
      • 0912 Species concentration vs. solution concentration
      • 0913 Weak electrolytes: Getting quantitative
    • Chapter 11: Dynamic chemical equilibrium >
      • 1100 Dynamic chemical equilibrium: Overview
      • 1101 Visualising dynamic chemical equilibrium
      • 1102 The jargon of chemical equilibrium
      • 1103 Equilibrium constants: The law of equilibrium
      • 1104 The law of equilibrium: an analogy
    • Chapter 22 Spectroscopy >
      • 2200 Spectroscopy: Overview and preview
      • 2201 Quantisation of forms of energy
      • 2202 Light: Wave-particle "duality"
      • 2203 Ultraviolet-visible spectroscopy
      • 2204 Beer’s law: How much light is transmitted?
    • Chapter 27 The greenhouse effect, climate change >
      • 2700 The greenhouse effect: overview
      • 2701 Is Earth in energy balance?
      • 2702 CO2 in the atmosphere before 1800
      • 2703 So little CO2! Pffft?
      • 2704 Does CO2 affect Earth's energy balance?
      • 2705 The "greenhouse effect"
      • 2706 Why does CO2 absorb radiation from Earth?
      • 2707 The "enhanced greenhouse effect"
      • 2708 Why doesn't CO2 absorb the radiation from the sun?
      • 2709 Why are N2 and O2 not greenhouse gases?
      • 2710 Doesn't water vapour absorb all the IR?
      • 2711 Carbon dioxide from our cars
      • 2712 The source of energy from combustion
      • 2713 Comparing fuels as energy sources
      • 2714 Methane: How does it compare as a GHG?
      • 2715 Different sorts of pollution of the atmosphere
      • 2716 "Acidification" of seawater
    • Chapter 27 Communicating chemistry >
      • 2700 Overview, preview
      • 2703 The jargon we use
  • TEACHERS' CORNER
    • T01 Communicating chemistry
    • T02 Beer's law
    • T03 Professional amnesia of the chemistry teaching professio
    • T04 Law of equilibrium
    • T05 Visusalizing dynamic chemical equilibrium
    • Information vs. knowledge
  • PERSONAL GALLERY
    • Family
    • Travel
    • Playful dolphins
    • The University of Western Australia
    • Kings Park
    • Perth
    • At work
    • 999 Thermodynamics